Adv Mater 2012, 24:720–723.CrossRef 26. Sadewasser S, Abou-Ras D, Azulay D, Baier R, Balberg I, Cahen D, Cohen S, Gartsman K, Ganesan K, Kavalakkatt J, Li W, Millo O, Rissom T, Rosenwaks Y, Schock H-W, Schwarzman A, Unold T: Nanometer-scale electronic and microstructural properties of grain boundaries in Cu(In, Ga)Se 2 . Thin Solid Films 2011, 519:7341–7346.CrossRef

27. Shin RH, Jo W, Kim D-W, Yun JH, Ahn S: Local current–voltage behaviors of preferentially and Omipalisib randomly textured Cu(In, Ga)Se 2 thin films investigated by conductive atomic force microscopy. Appl Phys A 2011, 104:1189–1194.CrossRef 28. Shin RH, Jeong AR, Jo W: Investigation of local electronic transport and surface potential distribution of Cu(In, Ga)Se 2 thin-films. Curr Appl Phys 2012, 12:1313–1318.CrossRef 29. Azulay D, Millo O, Balberg I, Schock HW, Visoly-Fisher I, Cahen D: Current routes in polycrystalline CuInSe 2 and Cu(In, Ga)Se 2 films. Sol Energy Mater Sol Cells 2007, 91:85–90.CrossRef 30. Li J, Mitzi DB, Shenoy VB: Structure and electronic properties of grain boundaries in earth-abundant photovoltaic absorber Cu 2 ZnSnSe 4 . ACS Nano 2011, 5:8613–8619.CrossRef Competing interests The authors Compound C supplier declare that they

have no competing interests. Authors’ contributions GYK, JRK, and WJ measured the electrical properties of the CZTSSe samples with scanning probe microscopy. DHS, DHK, and JKK made the CZTSSe samples by sputtering and subsequent selenization. All authors read and approved the final manuscript.”
“Background There is an increasing demand for next-generation

high-density non-volatile memory devices because flash memories are approaching their scaling limits. Among many candidates to replace the flash DOK2 memory devices, resistive random access memory (RRAM) is one of the promising candidates, owing to its simple metal-insulator-metal structure, fast switching speed, low-power operation, excellent scalability potential, and high density in crossbar structure [1–4]. Many switching materials such as TaO x [5–7], AlO x [8, 9], HfO x [10–15], TiO x [16, 17], NiO x [18–21], WO x [22, 23], ZnO x [24, 25], ZrO x [26–31], SrTiO3 [32, 33], SiO x [34, 35], and Pr0.7Ca0.3MnO3 [36, 37] have been studied by several groups. However, the rare-earth oxide such as Gd2O3 could be a promising resistive switching material because of its high resistivity, high dielectric permittivity (κ = 16), moderate energy gap (E g = Selleckchem CRT0066101 approximately 5.3 eV), and higher thermodynamic stability [38]. Recently, many researchers have reported the resistive switching properties by using Gd2O3 materials [38–40]. Cao et al. [38] have reported unipolar resistive switching phenomena using Pt/Gd2O3/Pt structure with a high RESET current of 35 mA. Liu et al. [39] have also reported unipolar resistive switching phenomena with a high RESET current of 10 mA in Ti/Gd2O3/Pt structure. Yoon et al.